Main Cast:
* Shahid Kapoor as Kabir Khan
* Shivani Tomar as Komal Chautala
* Sagarika Ghatge as Preeti Sabarwal
* Tanya Abrol as Bindia Naik
* Shilpa Shukla as Aliya Bose
* Anupam Kher as Mr. Singh (Coach's Father)
* Vijay Raaz as Mr. A.K. Chautala (Komal's Father)
* Rajesh Tailang as Balbir Singh (Assistant Coach)
* Chitrangada Singh as Gul Panag (Coach Kabir Khan's girlfriend)
* Seema Biswas as Kabir Khan's Mother
Supporting Cast:
* Jaya Bachchan as Jaya Bakshi (Indian Hockey Team's Manager)
* Dimple Kapadia as Rani (Kabir Khan's sister)
* Aamir Bashir as Coach Ajit Singh
* Pawan Malhotra as Captain K.P. Singh
* Kirron Kher as Kabir's Aunt
Note: "Chak De! India" featured a large ensemble cast, including many actors and actresses who played the members of the Indian women's hockey team.