Plug one end of the TRS cable into the guitar, and plug the other end into the "Input" jack on the amp.
Plug one end of another TRS cable into the "Line Out" jack on the amp, and plug the other end into the "Input" jack on the audio interface. This will route the guitar signal through the power amp and loudspeaker emulators.
Unplug the TRS cable from the "Line Out" jack, and plug it into the "Pre-amp Out" jack, if you wish to bypass the power amp and loudspeaker emulators. This will give your guitar a clean, undistorted sound.
Turn the "Pre-amp Volume" knob to adjust the level coming out of the "Pre-amp Out" jack, or turn the "Line Level" knob to adjust the level coming out of "Line Out."