However, I can provide some key episodes where he plays a significant role:
Early Episodes:
* Episode 2: We are introduced to Toshiro as the young captain of the 10th Division.
* Episode 5: He participates in his first major battle against the Hollows.
* Episodes 12-14: He takes center stage in the fight against the Soul Society traitor, Ichimaru Gin.
Aizen's Invasion:
* Episodes 130-134: He participates in the defense of Soul Society against Aizen's invasion force.
* Episodes 168-175: He plays a key role in the battle against Aizen.
Fullbring Arc:
* Episodes 232-241: He fights alongside the other captains against the Fullbringers.
* Episodes 254-257: He faces off against Tsukishima, a powerful Fullbringer.
Thousand-Year Blood War Arc:
* Episodes 307-313: He is involved in the initial confrontation with the Quincy.
* Episodes 319-325: He fights against Pernida, a powerful Quincy.
* Episodes 341-349: He participates in the final battle against Yhwach.
Other notable appearances:
* Episodes 118-122: He is featured in a flashback of his past, learning his Zanpakuto's Shikai.
This list gives you a good starting point. It's definitely worth watching those episodes to see Toshiro's character development and his impressive fighting abilities!