Here's how to move boulders in Pokémon Pearl:
1. Catch a Bibarel: You can find Bibarel in the Eterna Forest.
2. Level up Bibarel to learn "Move": Bibarel learns Move at level 22.
3. Use Bibarel's "Move" ability: Stand next to a boulder and use Bibarel's Move ability.
Remember, you can only move boulders that have a yellow ! mark above them.