* Dove Cameron as Mal, daughter of Maleficent
* Cameron Boyce as Carlos, son of Cruella de Vil
* Sofia Carson as Evie, daughter of the Evil Queen
* Booboo Stewart as Jay, son of Jafar
* Kenny Ortega as Doug
* Mitchell Hope as King Ben
* Brenna D'Amico as Jane
* Dianne Doan as Lonnie
* Zachary Gibson as Chad
* Jeffery Nordling as King Beast
* Kathy Najimy as Fairy Godmother
* Keegan Connor Tracy as Belle
* Melanie Paxson as Queen Leah
* Dan Payne as King Adam
* Wendy Raquel Robinson as Evil Queen's Wardrobe
* Maz Jobrani as Mr. Smee
There were also a number of other actors and actresses who had smaller roles in the film.