In the natural minor scale, semitones occur between scale degrees two and three and between scale degrees five and six. An A natural minor scale would include the notes A, B, C, D, E, F, G and A. The semitones occur between B and C and between E and F.
Harmonic minor scales contain semitones between scales degrees two and three, five and six, and seven and eight. An A harmonic minor scale contains the notes A, B, C, D, E, F, G sharp and A. The tone and a half between the sixth and seventh notes of this scale gives it a special, almost Middle Eastern, quality.
Melodic minor scales are unusual because the ascending form is different from the descending form. An ascending A melodic minor scale contains the pitches A, B, C, D, E, F sharp, G sharp and A. The semitones are between B and C and between G sharp and A. The descending A melodic minor scale has the pitches A, G, F, E, D, C, B and A, exactly the same as the natural minor scale.