You can only access the areas that the game's path allows, so you'll need to stick to the designated routes to progress through the level and encounter the various Pokémon.
If you're looking for specific Pokémon, you'll need to explore the rest of the River Level and try different tactics, such as using your Pester Ball, Flash, or specific items to attract them to your view.
Remember, exploration and experimentation are key to finding all the Pokémon and achieving the best photos in Pokémon Snap!