It's possible you're thinking of an item or concept from a different Pokémon game.
Could you please clarify what you're looking for? Perhaps you are thinking of:
* EXP. Share: This item is available in many Pokémon games, including Pokémon FireRed. It allows a Pokémon not in the battle to gain experience points (EXP) as if it were fighting.
* Evolution items: Some Pokémon evolve using specific items, such as a Thunderstone for Pikachu to evolve into Raichu.
Please let me know what you are trying to achieve, and I will do my best to help!