By Leveling Up:
* Level 1: Wrap
* Level 4: Vine Whip
* Level 7: Growth
* Level 10: Leaf Storm
* Level 13: Glare
* Level 16: Take Down
* Level 19: Solar Beam
* Level 22: Synthesis
* Level 25: Coil
* Level 28: Leaf Tornado
* Level 31: Substitute
* Level 34: Dragon Pulse
* Level 37: Energy Ball
* Level 40: Outrage
* Level 43: Giga Drain
* Level 46: Dazzling Gleam
* Level 49: Leaf Storm
* Level 52: Dragon Tail
* Level 55: Frenzy Plant
By TM/TR:
* TM06: Toxic
* TM10: Hidden Power
* TM11: Sunny Day
* TM15: Hyper Beam
* TM17: Protect
* TM21: Dazzling Gleam
* TM27: Return
* TM28: Frustration
* TM32: Double-Edge
* TM39: Rock Tomb
* TM42: Facade
* TM44: Rest
* TM45: Attract
* TM49: Sweet Scent
* TM50: Overheat
* TM52: Focus Blast
* TM55: Scald
* TM60: Quick Attack
* TM67: Substitute
* TM70: Flash Cannon
* TM87: Swagger
* TM90: Substitute
* TM91: Flash Cannon
* TM94: Surf
* TM100: Confide
* TR01: Work Up
* TR04: Calm Mind
* TR08: Will-O-Wisp
* TR10: Thunderbolt
* TR16: Earth Power
* TR38: Fire Blast
* TR42: Aerial Ace
* TR46: Iron Head
* TR48: Grass Knot
* TR50: Sludge Bomb
* TR51: Draco Meteor
* TR55: Shadow Ball
By Breeding:
* Egg Moves: Ancient Power, Leaf Storm, Poison Jab, and more.
By Tutor:
* Tutor Moves: Nature Power, Defog, Synthesis, and more.
Serperior excels in both offensive and defensive roles, boasting a great movepool to support its playstyle. Its access to powerful STAB moves like Leaf Storm, Solar Beam, and Giga Drain makes it a formidable offensive threat. It can also utilize moves like Coil, Substitute, and Protect to bolster its defensive capabilities.
Remember that the availability of moves might differ depending on the game generation you're playing in.