Methods of Learning Substitute:
* Level Up: Some Pokémon learn Substitute naturally as they level up.
* TM: Substitute can be taught through the TM010 (Substitute) in many games.
* Breeding: Some Pokémon can pass down Substitute to their offspring through breeding.
* Tutor: Some Pokémon can learn Substitute from a Move Tutor.
Finding the Pokémon:
* Serebii: This website has comprehensive lists of Pokémon moves, including Substitute. You can search by Pokémon name or the move itself to see which Pokémon learn it.
* Bulbapedia: Another great resource, Bulbapedia has detailed information on each Pokémon, including their movepools.
* In-Game Move Tutors: Check in-game move tutors for specific Pokémon that might be able to learn Substitute.
Unfortunately, I can't give you a complete list of all Pokémon that can learn Substitute. This is because the movepool for each Pokémon can vary across different generations of Pokémon games.
To find the specific Pokémon you're looking for, use the methods above!