The closest thing to Momiji protecting Tohru from Akito is in the Fruits Basket: Another manga. In that story, Momiji does intervene to protect Tohru from Akito's outburst, but it's not a direct confrontation. He calms Tohru down and helps her escape the situation.
It's important to remember that Momiji is a very gentle and empathetic character. He wouldn't physically confront Akito, even to protect Tohru. His actions are more about protecting her feelings and ensuring her safety.